By Paul Brumer, Stuart A. Rice, Aaron R. Dinner
This quantity of Advances in Chemical Physics is devoted, via the individuals, to Moshe Shapiro, previously Canada examine Chair in Quantum keep watch over within the division of Chemistry on the collage of British Columbia and Jacques Mimran Professor of Chemical Physics on the Weizmann Institute, who passed on to the great beyond on December three, 2013. It focuses totally on the interplay of sunshine with molecules, one in all Moshe’s longstanding clinical loves. even if, the big variety of themes lined during this quantity constitutes yet a small a part of Moshe’s great variety of clinical pursuits, that are good documented in over three hundred study guides and books.
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Additional resources for Advances in Chemical Physics Volume 159
Pressure dependence of the photooxidation of selected carbonyl compounds in air: n-butanal and n-pentanal,” J. Photochem. Photobiol. , 143: 169–179 (2001). 71. M. Richter, P. Marquetand, J. Gonzalez-Vazquez, I. Sola, and L. Gonzalez. “SHARC: ab initio molecular dynamics with surface hopping in the adiabatic representation including arbitrary couplings,” J. Chem. , 7: 1253–1258 (2011). 72. G. L. Cui and W. Thiel. “Generalized trajectory surface-hopping method for internal conversion and intersystem crossing,” J.
N. J. Pitts. Chemistry of the Upper and Lower Atmosphere. Academic Press, New York (2000). 2. P. J. Robinson and K. A. Holbrook. Unimolecular Reactions. Wiley, New York (1973). 3. R. G. Gilbert and S. C. Smith. Theory of Unimolecular and Recombination Reactions. Blackwell, Oxford (1990). 4. M. I. McCarthy, R. B. Gerber and M. Shapiro. Quantum-theory of the photodissociation of IBr adsorbed on an MgO(0 0 1) surface. J. Chem. , 92: 7708–7715 (1990). 5. R. Atkinson. “Gas-phase tropospheric chemistry of organic-compounds – a review,” Atmos.
It was found that the absorption spectra of N2 O for excitation starting from vibrationless ground state molecules, or from vibrationally excited stretching modes, (1,0,0) and (0,0,1), differ drastically in shape. For vibrationless ground state and for vibrationally excited molecules, the spectrum consisted of a single symmetric peak and of two unequal peaks, respectively, which was attributed to the energy dependence of the individual transition probabilities. Moreover, the initial state of N2 O also affected the population of the N2 photofragment.